Makiko Hattori1, Masatoshi Saito1, Kunihiko Okajima1 and Kenji Kamide2Top of pageAbstractAn attempt was made to evaluate molecular parameters of poly(hexamethyleneadipamide) (nylon 6,6) in mixture of calcium chloride and methanol with various calcium chloride concentrations (weight fraction Wca against weight of the solvent mixture) using light scattering method. Dissolved state of the polymer was discussed in connection with the chain conformation based on data of viscosity, adiabatic compressibility, infrared (IR) spectra and 1H and 13C NMR spectra. The second virial coefficient A2, obtained by the light scattering method, remarkably decreases with a decrease of Wca below 0.15 and is expected to become zero at Wca of ca.

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